Saturday, 21 November 2015

Groundwater Imaging with NMR/MRI

http://www.vista-clara.com/instruments/gmr/

Uses the same principles as medical MRI except uses the EArth's magnetic field in place of an electromagnet.



This specific company says their tech can:

"GMR MEASUREMENTS PROVIDE

  • Non-invasive direct detection of groundwater
  • Spatial resolution of hydrogeologic parameters in 1D, 2D, or even 3D
  • Quantitative determination of water content and porosity
  • Estimation of mobile versus bound water content
  • Estimation of relative or calibrated hydraulic conductivity and transmissivity
  • Investigation to depths up to 150 meters

GMR APPLICATIONS IN HYDROLOGY INCLUDE

  • Groundwater exploration and well site selection
  • Determination of water storage and specific yield
  • “Virtual pump testing”: estimation of aquifer properties
  • Imaging of preferential flow zones (e.g. fractures, karst conduits, paleochannels)
  • Parameterization of groundwater models at local to basin scales
  • Integration of logging and surface-based NMR measurements"


Shows 2D groundwater imaging 


Shows mobile and bound water 

This may be useful to see changes in ground water distribution and possible induced flows as a result of fracking.

I think that the hydrogen in water and methane will respond differently in MRI so detection of methane in water may be possible.

Friday, 20 November 2015

Paper about Migration of water - PET and CT comparision

·      Comparison of Positron Emission Tomography and X-Ray Radiography for Studies of Physical Processes in Sandstone

PET can be applied by labelling the substance of interest with a positron emitting radionuclide. Can be short-lived isotopes e.g C11, O15, N13 and F18 or, longer lived water soluble isotopes e.g. Ga and Co for studying slower processes. This study looks at the migration of water in sandstone with water-soluble tracers. They used tracers of two different sizes since flooding depends on permeability. 


Paper about Migration of Fluids through Rocks - PET with CT and MRI comparisions

·       Evaluation of Positron-Emission-Tomography for Visualisation of Migration Processes in Geomaterials

Transport of a fluid through rock depends on the porous or fractured structure of the material. PET can provided a time and space evolution of an injected tracer through a material.  Comparatively high resolution CT yields structural information. NMR can also be used to study process but has a much lower resolution than PET. This study looked at evolution of a flow injected at different rates into the material. At slower speeds there is more lateral dispersion of the fluid through the material.


(http://www.researchgate.net/publication/248550237_Evaluation_of_positron-emissiontomography_for_visualization_of_migration_process_in_geomaterials._Phys_Chem_Earth_33937)

Friday, 13 November 2015

What is fracking.

What is fracking?
Fracking is the process of drilling down into the earth before a high-pressure water mixture is directed at the rock to release the gas inside. Water, sand and chemicals are injected into the rock at high pressure which allows the gas to flow out to the head of the well.
The process is carried out vertically or, more commonly, by drilling horizontally to the rock layer. The process can create new pathways to release gas or can be used to extend existing channels.
What are the advantages of fracking?
Fracking allows drilling firms to access difficult-to-reach resources of oil and gas. In the US it has significantly boosted domestic oil production and driven down gas prices. It is estimated to have offered gas security to the US and Canada for about 100 years, and has presented an opportunity to generate electricity at half the CO2 emissions of coal.
The industry suggests fracking of shale gas could contribute significantly to the UK's future energy needs. A report by the Energy and Climate Change Committee in April said shale gas in the UK may help to secure energy supplies, but may not bring down gas prices.



Shale gas is natural gas trapped in impermeable shale rock, as opposed to conventional natural gas deposits, which are trapped below a layer of impermeable rock. Therefore simply drilling down to it is not enough. The rock has to be cracked open at high pressure or ‘fractured’ to get the gas out. Fracking involves drilling up to around 2,500 metres vertically, then laterally out for 1,000 -3,000 metres. The gap between the borehole liner and the surrounding rock is then sealed up with concrete. The well casing is perforated to allow fracking fluid to get into the rock, and gas to get out. Then, on a typical well, up to 10 million litres of water containing lubricating fluids and other additives, and sand, are pumped into the borehole under extremely high pressures. This opens up cracks in the shale for up to 50 metres. The cracks are kept open by the sand particles when the pressure is released, so the shale gas can escape. A well head is then installed to capture the released gas. The drilling and fracking equipment is then taken away.





Risks:
Contaminating groundwater (methane dissolves in the aquifer)
Release of greenhouse gases: methane
Very large consumption of energy
Improper or insufficient cement casing leads to methane leaks
More than 750 chemicals are used:
              -they reduce friction and shorten drilling time
              -increase the viscosity and serve as antibacterial agents
Fracturing fluids remaining underground have the potential to migrate into shallow ground water sources over time
What is Fracking?
Fracking is shorthand for hydraulic fracturing, a type of drilling that has been used commercially for 65 years. Today, the combination of advanced hydraulic fracturing and horizontal drilling, employing cutting-edge technologies, is mostly responsible for surging U.S. oil and natural gas production.
Hydraulic fracturing involves safely tapping shale and other tight-rock formations by drilling a mile or more below the surface before gradually turning horizontal and continuing several thousand feet more. Thus, a single surface site can accommodate a number of wells. Once the well is drilled, cased and cemented, small perforations are made in the horizontal portion of the well pipe, through which a typical mixture of water (90 percent), sand (9.5 percent) and additives (0.5 percent) is pumped at high pressure to create micro-fractures in the rock that are held open by the grains of sand. Additives play a number of roles, including helping to reduce friction (thereby reducing the amount of pumping pressure from diesel-powered sources, which reduces air emissions) and prevent pipe corrosion, which in turn help protect the environment and boost well efficiency.









Uses so far.

Pipe Inspection

Rock structure examination

how cracks form in different materials according to structure

Discovery of different nuclei in an area with core plug SPECT

Particle Tracking in rock samples

Thursday, 12 November 2015

Possible use for PET

as the gas is transported through pipes to storage the pipes can get damaged, and the insides eroded and cracked.

magnetic particle inspection uses small magnetic particles to stick to and show faults in welding and metalwork due to a changing magnetic field over he surface of the metal and is widely used due to its non-intrusive nature.
Image result for magnetic particle inspection
http://me.aut.ac.ir/staff/solidmechanics/alizadeh/Magnetic%20Particle%20Inspection.htm
the non-radioactive kind is limited by the fact that contact must be made with the damaged surface, this may not always be positive however.

magnetic particles with inserted beta emitters will form the same structure on the faults but will be on the inside of the pipe and detectable using PET and if part is too damaged it can be removed.

A scanner able to do this job has been developed in Birmingham.

References
Nde-ed.org, (2015). Intro to MPI. [online] Available at: https://www.nde-ed.org/EducationResources/CommunityCollege/MagParticle/Introduction/introduction.htm [Accessed 12 Nov. 2015].
Np.ph.bham.ac.uk, (2015). Positron Imaging Centre. [online] Available at: http://www.np.ph.bham.ac.uk/pic/uses_mob_detector [Accessed 13 Nov. 2015].


Description of PET and types of PET

Uses Beta decay which emits a positron which annihilates with an electron.

http://tech.snmjournals.org/cgi/content-nw/full/29/1/4/F1
Detector surrounds the emission site and emitted photons are received by each side of the detector.
The location of each annihilation is inferred from a line integral.
This is done using many annihilations to produce an estimated shape of the positron rich area.


PEPT Positron Emission Particle Tracking
Able to track a tracer particle with velocity up to 2m/s.
Can locate particle to within 5mm 250 times each second.
Uses a detector on each side of the sample and can follow the tracer on rails.
tracer particle roughly 1mm diameter.

though promising for its ability to track particles, the use seems limited to rolling drum flow and twin screw extruders.

SPECT Single Photon Emission Computational Tomography
Used to give true 3D images presented as cross sections
Can make use of multiple energy windows to dual tracer imaging. (more than 2?) imaging multiple radionuclides.


References:

Np.ph.bham.ac.uk, (2015). Positron Imaging Centre. [online] Available at: http://www.np.ph.bham.ac.uk/pic/pept [Accessed 12 Nov. 2015].
Rahmim, A. and Zaidi, H. (2008). PET versus SPECT: strengths, limitations and challenges. Nuclear Medicine Communications, 29(3), pp.193-207.

Wednesday, 4 November 2015

Applications in Geoscience

            CT
Paper: Applications of X-ray computed tomography in the geosciences
“Abstract: X-ray computed tomography (CT) is a non-destructive technique with wide applications in various geological disciplines. It reveals the internal structure of objects, determined by variations in density and atomic composition. Large numbers of parallel 2D sections can be obtained, which allows 3D imaging of selected features. Important applications are the study of porosity and fluid flow, applied to investigations in the fields of petroleum geology, rock mechanics and soil science. Expected future developments include the combined use of CT systems with different resolutions, the wider use of related X-ray techniques and the integration of CT data with results of compatible non-destructive techniques.”

Webpage: http://www.geochemsoc.org/publications/geochemicalnews/gn132jul07/computedtomographyappliedt/

            PET and CT

Paper: Combined positron emission tomography and computed tomography to visualize and quantify fluid flow in sedimentary rocks

“Abstract: Here we show for the first time the combined positron emission tomography (PET) and computed tomography (CT) imaging of flow processes within porous rocks to quantify the development in local fluid saturations. The coupling between local rock structure and displacement fronts is demonstrated in exploratory experiments using this novel approach. We also compare quantification of 3-D temporal and spatial water saturations in two similar CO2storage tests in sandstone imaged separately with PET and CT. The applicability of each visualization technique is evaluated for a range of displacement processes, and the favorable implementation of combining PET/CT for laboratory core analysis is discussed. We learn that the signal-to-noise ratio (SNR) is over an order of magnitude higher for PET compared with CT for the studied processes.”

Comparison of PET and CT in Physical Processes in Sandstones
“Abstract: The migration of moisture in cores of porous homogeneous sandstone of Ledian age (Belgian Eocene, Tertiary) is monitored with PET (Positron Emission Tomography) and micro-focus X-ray radiography. In the case of PET, a nuclear medical imaging technique, 55Co-EDTA (Ethylenediamine Tetraacetic acid) and R-18F were used as water-soluble tracers. The X-ray projection method has evolved from the better-known medical technique and allows a fast and accurate determination of the two-dimensional transient moisture content profiles. Results indicate that both techniques can deliver important information concerning physical processes in situ
Source:http://www.researchgate.net/publication/223215827_Comparison_of_Positron_Emission_Tomography_and_X-ray_radiography_for_studies_of_physical_processes_in_sandstone

       PET

Paper: The influence of deformation bands upon fluid flow using profile permeametry and positron emission tomography

“Abstract: Cataclastic deformation bands are significant discontinuities in sandstone reservoirs since they have dramatically reduced porosity and permeability relative to their host rock, despite their mm-scale displacements. Consequently, these discontinuities often have a large impact upon the flow of fluids at both micro and macro-scales. The effect of this impact in highly porous sandstone has been analyzed using a range of novel and conventional techniques, including pressure decay profile permeametry (PDPK) and positron emission tomography (PET)......  PET was used to monitor fluid flow as a function of pore volume of a sandstone plug containing deformation bands, demonstrating the direct effect of deformation bands as a potential barrier to fluid flow. The results of this study provide a detailed characterization of deformation bands at high resolution, which can be included in advanced reservoir simulation models.

Staßfurt: fluid transport in rock salt - spatial distribution and dynamics




     MRI

Paper: Magnetic resonance sounding: new method for ground water assessment.

“Abstract: The advantage of magnetic resonance sounding (MRS) as compared to other classical geophysical methods is in its water selective approach and reduced ambiguity in determination of subsurface free water content and hydraulic properties of the media due to the nuclear magnetic resonance (NMR) principle applied……”
Source: http://www.ncbi.nlm.nih.gov/pubmed/15035592